Performances of Ludai (Sapium Baccatum) and Kelempayan (Neolamarckia Cadamba) after Acetylation

Authors

  • Siti Rafedah Abdul Karim Faculty of Applied Science, Universiti Teknologi MARA 40450 Shah Alam Selangor, Malaysia
  • Yanti Abdul Kadir Research Officer, Forest Research Institute Malaysia, Kepong, 52109 Selangor Malaysia
  • Azrena Abdul Karim Faculty of Applied Science, Universiti Teknologi MARA 40450 Shah Alam Selangor, Malaysia

DOI:

https://doi.org/10.21834/e-bpj.v9iSI17.5977

Keywords:

Acetylation, Weight percent gain, Hydroxyl substitution, Volume change

Abstract

The study changed the chemicals that make up Ludai (Sapium Baccatum) and Kelempayan (Neolamarckia Cadamba) molecules that have been modified with acetic anhydride. The wood species was treated at 80°C, 100°C, and 120°C.  The changes were assessed by replacing the WPG and OH groups.  The WPG range is 3%–16%, and therefore, at 16%, Ludai had the highest WPG, while Kelempayan had 14%.  At 120°C, a 15% weight per gallon (WPG) solution changed Kelempayan volume by 9%. The Ludai volume changed 5.5% under the same conditions. The Ludai and Kelempayan had the highest OH-substitution rate at 120°C, 3.5–4 mmoles/g.

References

Antonios N. Papadopoulos, Dimitrios N. Bikiaris, ,Athanasios C. Mitropoulos, andGeorge Z. Kyzas. (2019) Nanomaterials and Chemical Modifications for Enhanced Key Wood Properties: A Review. Nanomaterials 2019, 9(4), 607 DOI: https://doi.org/10.3390/nano9040607

Azizul Ishak, Siti Rafedah A.K and Hashim W.S. (2013). Mechanical and Physical Properties of Particleboard Made from Silane and NaOH Modified Kelempayan (Neolamarckia Cadamba) Particles. Advanced Materials Research Vol. 812 (2013) pg 169-174. Trans Tech Publications, Switzerland DOI: https://doi.org/10.4028/www.scientific.net/AMR.812.169

Chang, H.T & Chang, S.T. (2002). Moisture excluding efficiency and dimensional stability of wood improved by acylation. Bioresources Technology 85, 201-204 DOI: https://doi.org/10.1016/S0960-8524(02)00085-8

Gauss, C., Kadivar, M., Harries, K. A., & Savastano, H. (2021). Chemical modification of Dendrocalamus asper bamboo with citric acid and boron compounds: Effects on the physical-chemical, mechanical and thermal properties. Journal of Cleaner Production, 279, 123871. https://doi.org/10.1016/j.jclepro.2020.123871 DOI: https://doi.org/10.1016/j.jclepro.2020.123871

Hamid, N. H., Sulaiman, O., Mohammad, A., & Ahmad Ludin, N. (2012). The Decay Resistance and Hyphae Penetration of Bamboo Gigantochloa scortechinii Decayed by White and Brown Rot Fungi . International Journal of Forestry Research, 2012, 1–5. https://doi.org/10.1155/2012/572903 DOI: https://doi.org/10.1155/2012/572903

Hill, C.A.S (2008). The reduction in the fibre saturation point of wood due to chemical modification using anhydride reagent. Holzforschung 62, 423-428 DOI: https://doi.org/10.1515/HF.2008.078

Hill, C.A.S., and Ormondroyd, G.A., Siti Rafidah, K., Forster, S., Jones, D., Suttie, E and Howard, N (2005). The Decay Resistance of Anhydride Modified Wood: A study of the Mechanisms. Proceeding of the Second European Conference on Wood Modification, Gottingen, Germany, 100-107.

Hill, C.A.S. Papadopolous, A.N. Payne, D. (2004). Chemical Modification Employed as A Means of Probing The Cell Wall Micropore of Pine Sapwood. Wood Sci Technology 37, 475-488 DOI: https://doi.org/10.1007/s00226-003-0193-5

Hill C.A.S and Jones, D. (1999). Dimensional changes in Corsican Pine sapwood due to chemical modification with linear chain anhydrides. Holzforschung 53 (3), 267-271 DOI: https://doi.org/10.1515/HF.1999.045

Hill, C.A.S. and Hillier, J.G (1999). Studies of the reaction of carboxylic acid anhydrides with wood. Experimental determination and modelling of kinetics profiles. Phys.Chem.Phys.Chem 1, 1569-1576 DOI: https://doi.org/10.1039/a809830a

Hill C.A.S & Jones, D. (1996). The dimensional stabilisation of Corsican Pine sapwood by reaction with carboxylic acid anhydrides. Holzforschung 50 (5), 457-462 DOI: https://doi.org/10.1515/hfsg.1996.50.5.457

Kwon, J.H., Hill, C.A.S., Ormondroyd, G.A and Siti Rafedah, A.K. (2007) Changes in the Cell Wall Volume of a Number of Wood Species Due to Reaction with Acetic Anhydride. Holzforschung 61 (2), 138-142. De Gruyter DOI: https://doi.org/10.1515/HF.2007.025

Mashitah, J and Siti Rafedah, A.K (2012). Acetylation of Ludai (Sapium baccatum spp.) with Temperature Dependence.International Seminar on Analytical Sciences 2012. Medan, Indonesia. 12-13 November 2012.

Mingming He, Dandan Xu, Changgui Li, Yuzhen Ma, Xiaohan Dai, Xiya Pan, Jilong Fan, Zaixin He, Shihan Gui, Xiaoying Dong and Yongfeng Li. (2020). Cell Wall Bulking by Maleic Anhydride for Wood Durability Improvement. Forests, 11(4), 367. DOI: https://doi.org/10.3390/f11040367

Papadopolous, A.N. Hill, and C.A.S. Grakaveli, A. (2004). Analysis of the swelling behaviour of chemically modified softwood: A Novel Approach. Holz Roh Werkst 62, 107-112 DOI: https://doi.org/10.1007/s00107-003-0448-8

Rowell, R.M. and Ellis, W.D. (1978). Determination of the dimensional stabilisation of wood using the water soak method. Wood Fibre Sci 10, 11-18

Rowell, R.M. (1993). Protection of wood against biodegradation by chemical modification. In: Kennedy, J.F. Phillips, G.O. William, P.A (Eds), Cellulosic,Pulp, Fiber and Environmental Aspect. Ellis Hardwood, New York (Chapter 70)

Rowell, R.M (2005). Chemical Modification of Wood. CRC Press LLC. DOI: https://doi.org/10.1201/9780203492437-18

Siti Rafedah Abdul Karim, Shahlinney Lipeh and Azrai Suzazsuzuludin. (2020). Resistance of Dendrocalamus asper (Buluh Betong) Treated with Plant Extracts to Mold. International Journal of Agriculture, Forestry and Plantation, Vol. 10 (Sept), ISSN 2462-1757

Siti Rafedah, A.K. (2007). Chemical Modification of Rubberwood (Hevea Brasiliensis Muell. Arg) with Acetic Anhydride and Hexanoic Anhydride. PhD Thesis. School of Environment and Natural Resources, University of Wales, Bangor United Kingdom

Siti Rafidah, K., Hill, C.A.S., and Ormondroyd, G.A. (2006). Dimensional stabilization of Rubberwood (Hevea Brasiliensis) with acetic or hexanoic anhydride. Journal of Tropical Forest Science 18 (4), 261-268

Skaar, C. (1984). Wood-Water relationships. In. Rowell, R.M (Ed), The chemistry of solid wood.American Chemical Society, Washington, DC (Chapter 3) DOI: https://doi.org/10.1021/ba-1984-0207.ch003

Yaumil, H. F and Siti Rafedah, A.K (2012). A preliminary Study of the Potential of Acetylated Kelempayan without Catalyst. International Seminar on Analytical Sciences 2012. Medan, Indonesia. 12-13 November 2012.

Yue Wang, Tianxiang Wang , Roberto Crocetti , Magnus Wålinder. (2022). Experimental investigation on mechanical properties of acetylated birch plywood and its angle-dependence. Construction and Building Materials. 344(2022). 1-10 DOI: https://doi.org/10.1016/j.conbuildmat.2022.128277

Saisai Huang, et al (2019). Combined Chemical Modification of Bamboo Material Prepared Using Vinyl Acetate and Methyl Methacrylate: Dimensional Stability, Chemical Structure, and Dynamic Mechanical Properties. Polymers 2019, 11, 1651; pp1-14, doi:10.3390/polym11101651. DOI: https://doi.org/10.3390/polym11101651

Wenzhai Bi , Haitao Li, David Hui , Milan Gaff , Rodolfo Lorenzo , Ileana Corbi , Ottavia Corbi and Mahmud Ashraf. (2021). Effects of chemical modification and nanotechnology on wood properties. Nanotechnology Reviews. Volume 10 Issue 1 978-1008 DOI: https://doi.org/10.1515/ntrev-2021-0065

Downloads

Published

2024-01-07

How to Cite

Abdul Karim, S. R., Abdul Kadir, Y., & Abdul Karim, A. (2024). Performances of Ludai (Sapium Baccatum) and Kelempayan (Neolamarckia Cadamba) after Acetylation. Environment-Behaviour Proceedings Journal, 9(SI17), 577–583. https://doi.org/10.21834/e-bpj.v9iSI17.5977